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Construction of nitrogen-doped carbon cladding LiMnO film electrode with enhanced stability for electrochemically

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 2050-2060 doi: 10.1007/s11705-023-2343-7

摘要： Reducing the dissolution of Mn from LiMn2O4 (LMO) and enhancing the stability of film electrodes are critical and challenging for Li+ ions selective extraction via electrochemically switched ion exchange technology. In this work, we prepared a nitrogen-doped carbon cladding LMO (C-N@LMO) by polymerization of polypyrrole and high-temperature annealing in the N2 gas to achieve the above purpose. The modified C-N@LMO film electrode exhibited lower Mn dissolution and better cyclic stability than the LMO film electrode. The dissolution ratio of Mn from the C-N@LMO film electrode decreased by 42% compared to the LMO film electrode after 10 cycles. The cladding layer not only acted as a protective layer but also functioned as a conductive shell, accelerating the migration rate of Li+ ions. The intercalation equilibrium time of the C-N@LMO film electrode reached within an hour during the extraction of Li+ ions, which was 33% less compared to the pure LMO film electrode. Meanwhile, the C-N@LMO film electrode retained evident selectivity toward Li+ ions, and the separation factor was 118.38 for Li+ toward Mg2+ in simulated brine. Therefore, the C-N@LMO film electrode would be a promising candidate for the recovery of Li+ ions from salt lakes.

关键词： LiMn2O4     lithium extraction     surface coating     cyclic stability     Mn dissolution    

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An enhanced damage plasticity model for predicting the cyclic behavior of plain concrete under multiaxial

Mohammad Reza AZADI KAKAVAND, Ertugrul TACIROGLU

《结构与土木工程前沿（英文）》 2020年 第14卷 第6期   页码 1531-1544 doi: 10.1007/s11709-020-0675-7

摘要： Some of the current concrete damage plasticity models in the literature employ a single damage variable for both the tension and compression regimes, while a few more advanced models employ two damage variables. Models with a single variable have an inherent difficulty in accounting for the damage accrued due to tensile and compressive actions in appropriately different manners, and their mutual dependencies. In the current models that adopt two damage variables, the independence of these damage variables during cyclic loading results in the failure to capture the effects of tensile damage on the compressive behavior of concrete and vice-versa. This study presents a cyclic model established by extending an existing monotonic constitutive model. The model describes the cyclic behavior of concrete under multiaxial loading conditions and considers the influence of tensile/compressive damage on the compressive/tensile response. The proposed model, dubbed the enhanced concrete damage plasticity model (ECDPM), is an extension of an existing model that combines the theories of classical plasticity and continuum damage mechanics. Unlike most prior studies on models in the same category, the performance of the proposed ECDPM is evaluated using experimental data on concrete specimens at the material level obtained under cyclic multiaxial loading conditions including uniaxial tension and confined compression. The performance of the model is observed to be satisfactory. Furthermore, the superiority of ECDPM over three previously proposed constitutive models is demonstrated through comparisons with the results of a uniaxial tension-compression test and a virtual test.

关键词： damage plasticity model     plain concrete     cyclic loading     multiaxial loading conditions    

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Isogeometric analysis of coupled thermo-elastodynamic problems under cyclic thermal shock

Asghar AMANI DASHLEJEH

《结构与土木工程前沿（英文）》 2019年 第13卷 第2期   页码 397-405 doi: 10.1007/s11709-018-0473-7

摘要： The isogeometric analysis (IGA) method was extended for the solution of the coupled thermo-elastodynamic equations. The dimensionless formulation was accepted in discretization of the uncoupled and coupled thermoelasticity equations and the Generalized Newmark method was used in the time integration procedure. First, the performance of the proposed method was verified against a two-dimensional benchmark example subjected to constant thermal shock with available exact analytical solutions. Then a two-dimensional half-space benchmark example under thermal shock was solved. Finally, cyclic thermal shock (CTS) loading was applied on the half-space problem. The results dedicated that IGA can be used as a suitable approach in the analysis of the general thermomechanical problems.

关键词： isogeometric analysis     coupled thermo-elastodynamic     dynamic analysis     generalized newmark     cyclic thermal shock    

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Prediction of cyclic large plasticity for prestrained structural steel using only tensile coupon tests

Liang-Jiu JIA, Tsuyoshi KOYAMA, Hitoshi KUWAMURA

《结构与土木工程前沿（英文）》 2013年 第7卷 第4期   页码 466-476 doi: 10.1007/s11709-013-0219-5

摘要： Cold-formed steel members, which experience complicated prestrain histories, are frequently applied in structural engineering. This paper aims to predict cyclic plasticity of structural steels with tensile and compressive prestrain. Monotonic and cyclic tests on hourglass specimens with tensile and compressive prestrain are conducted, and compared with numerical simulations using the Chaboche model. Two approaches are taken in the simulation. The first requires only the monotonic tensile test data from the prestrained steels, and the second requires both the monotonic tensile test data from the virgin steel and the prestrain histories. The first approach slightly overestimates the compressive stress for specimens with tensile prestrain, while the second approach is able to accurately predict the cyclic plasticity in specimens with tensile and compressive prestrain.

关键词： cyclic plasticity     prestrain     Chaboche model     mild steel    

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循环双谱及在周期平稳类故障中的应用

苏中元,贾民平,许飞云,胡建中

《中国工程科学》 2006年 第8卷 第9期   页码 57-60

摘要：

论述了未知循环频率的周期平稳信号循环双谱的估计方法；研究了在循环双谱的循环累积量计算中涉及变量的简化存储方法，提出了该变量矩阵是对称阵，通过算法可以三角阵的元素来表述，克服了循环双谱传统估计方法计算量较大的缺陷，提高了运算效率；提出了循环双谱对调相故障信号的分析能力，以及对加性噪声的处理能力，仿真并验证了该方法的有效性，并将其应用于旋转机械状态分析。

关键词： 周期平稳     循环双谱     滞后积    

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Experimental research on seismic behavior of recycled concrete frame under varying cyclic loading

SUN Yuedong, XIAO Jianzhuang, ZHOU Deyuan

《结构与土木工程前沿（英文）》 2008年 第2卷 第4期   页码 302-308 doi: 10.1007/s11709-008-0050-6

摘要： A study is conducted on the seismic behavior of one natural concrete frame and two recycled concrete frames with 100% recycled coarse aggregate whose scales are 1:2 entirely, and a comparative study is conducted under low-reversed cyclic lateral loading and different vertical loading. This work aims to estimate the failure mechanism, hysteresis loops, displacement ductility, deterioration of strength and stiffness and energy dissipation of recycled concrete frames under low-reversed cyclic loading as well as the influence of different vertical loading. Analysis on the basis of the experiment proves that it is entirely feasible to apply recycled concrete to practical engineering for the sake of its good seismic behaviors. Theoretical base is provided for further study and practical application of recycled concrete structure.

关键词： different     aggregate     stiffness     practical application     % recycled    

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Cyclic behavior of prefabricated reinforced concrete frame with infill slit shear walls

Kui XIAO,Qilin ZHANG,Bin JIA

《结构与土木工程前沿（英文）》 2016年 第10卷 第1期   页码 63-71 doi: 10.1007/s11709-015-0294-x

摘要： A composite structural system consisting of prefabricated reinforced concrete frame with infill slit shear walls (PRCFW), with good ductility, is a new type of earthquake resistant structure. Pseudo-static tests were performed to evaluate the seismic behavior of the PRCFW system. Two one-bay, two-story PRCFW specimens were both built at one-half scale. Additional computational research is also conducted to enhance the nonlinear analytical capabilities for this system. Combined with the concrete damaged plastic (CDP) model provided by finite element program ABAQUS and the constitutive model of concrete proposed by Chinese code, the damage process of the PRCFW structure under cyclic load is simulated. The simulated results show a good agreement with the test data, the dynamic behavior of the PRCFW system can be simulated sufficiently accurate and efficient to provide useful design information. The experimental and numerical study show that this system has the potential to offer good ductility and energy absorption capacity to dissipate input energy, and stiffness adequate for controlling drift for buildings located in earthquake-prone regions.

关键词： slit shear wall     constitutive model     cyclic     seismic     damage    

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特高含水期分层段周期注采技术研究与实践认识

姜振海

《中国工程科学》 2012年 第14卷 第4期   页码 77-82

摘要：

针对萨北开发区油层沉积特点及特高含水期剩余油分布特点，以水动力学原理为指导，在已有周期注水实践经验的基础上，结合数值模拟进行机理研究，优化周期注采方式及各项参数，引入了分层段交叉注采改变液流方向改善开发效果的做法，在实践中取得了较好的效果。

关键词： 周期注水     周期采油     方式优化     参数优选    

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Experimental investigation of the influence on static and cyclic deformation of structural soft clay

CHEN Yunmin, CHEN Yingping, HUANG Bo

《结构与土木工程前沿（英文）》 2007年 第1卷 第4期   页码 422-429 doi: 10.1007/s11709-007-0057-4

摘要： This paper presents the experimental results performed to study the static and cyclic deformation behavior of undisturbed and remolded soft clays sampling from Xiaoshan. The consolidation tests indicated that the vertical strains of

关键词： consolidation     deformation     experimental     undisturbed    

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Numerical evaluation of group-pile foundation subjected to cyclic horizontal load

Youngji JIN, Xiaohua BAO, Yoshimitsu KONDO, Feng ZHANG,

《结构与土木工程前沿（英文）》 2010年 第4卷 第2期   页码 196-207 doi: 10.1007/s11709-010-0021-6

摘要： In this paper, three-dimensional (3D) finite element analyses of a real-scale group-pile foundation subjected to horizontal cyclic loading are conducted using a program named DBLEAVES. In the simulations, nonlinear behaviors of ground and piles are described by subloading model and the axial-force dependent model (AFD model) which considered the axial-force dependency in the nonlinear moment-curvature relations. In order to consider the influence of an effective stress path on the prediction of the group-pile foundation, the analyses are conducted within the framework of the soil-water coupling method with finite-difference and finite-element regime. The material parameters of soils are determined based on conventional triaxial drained compression tests on undisturbed and remolded specimens. The applicability of the proposed numerical method is encouraging, and therefore, it is quite confident to say that the method can be used to predict the mechanical behaviors of group-pile foundation to a satisfactory accuracy, particularly with the effective stress analysis.

关键词： group-pile foundation     real-scale cyclic loading test     three-dimensional finite element method (3D-FEM)     soil-water coupling analysis     undisturbed and remolded specimens    

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Compressive and cyclic flexural response of double-hooked-end steel fiber reinforced concrete

Demewoz W. MENNA; Aikaterini S. GENIKOMSOU; Mark F. GREEN

《结构与土木工程前沿（英文）》 2022年 第16卷 第9期   页码 1104-1126 doi: 10.1007/s11709-022-0845-x

摘要： Recent developments on high-performance double-hooked-end steel fibers have enhanced the wide applications of steel fiber reinforced concrete (SFRC). This study presents the compressive properties and the cyclic flexural performance of the SFRC that were experimentally examined. Three different double-hooked-end steel fibers at 0.25%, 0.5%, 0.75%, and 1% volume fractions were considered. All fiber types had similar length to diameter ratios, while the first two fiber types had similar anchorage mechanisms (4D) and tensile strength and the third type had different anchorage mechanism (5D) and a higher tensile strength. The increased volumetric ratio of the fibers increased the post-peak compressive strain (ductility), the tensile strength, and the cyclic flexural strength and cumulative energy dissipation characteristics of the SFRC. Among the 4D fibers, the mixtures with the larger steel fibers showed higher flexural strength and more energy dissipation compared to the SFRCs with smaller size fibers. For 1% steel fiber dosage, 4D and 5D specimens showed similar cyclic flexural responses. Finally, a 3D finite element model that can predict the monotonic and cyclic flexural responses of the double-hooked-end SFRC was developed. The calibration process considered the results obtained from the inverse analysis to determine the tensile behavior of the SFRC.

关键词： steel fiber reinforced concrete     fiber geometry     cyclic loading     energy dissipation     finite element modeling     inverse analysis    

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Seismic response of precast reinforced concrete wall subjected to cyclic in-plane and constant out-of-plane

《结构与土木工程前沿（英文）》 2021年 第15卷 第5期   页码 1128-1143 doi: 10.1007/s11709-021-0753-5

摘要： This paper provides insight into the seismic behavior of a full-scale precast reinforced concrete wall under in-plane cyclic loading combined with out-of-plane loading replicated by sand backfill to simulate the actual condition of basement walls. The tested wall exhibited flexural cracks, owing to the high aspect ratio and considerable out-of-plane movement due to lateral pressure from the backfill. The wall performed satisfactorily by exhibiting competent seismic parameters and deformation characteristics governed by its ductile response in the nonlinear phase during the test with smaller residual drift. Numerical analysis was conducted to validate experimental findings, which complied with each other. The numerical model was used to conduct parametric studies to study the effect of backfill density and aspect ratio on seismic response of the proposed precast wall system. The in-plane capacity of walls reduced, while deformation characteristics were unaffected by the increase in backfill density. An increase in aspect ratio leads to a reduction in in-plane capacity and an increase in drift. Curves between the ratio of in-plane yield capacity and design shear load of walls are proposed for the backfill density, which may be adopted to determine the in-plane yield capacity of the basement walls based on their design shear.

关键词： precast wall     basement wall     out-of-plane response     quasi-static test     sand backfill     seismic parameters    

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Design of a cyclic inhibitory CPG controller for the locomotion of a snakelike robot

LU Zhen-li, MA Shu-gen, LI Bin, WANG Yue-chao

《机械工程前沿（英文）》 2006年 第1卷 第4期   页码 396-402 doi: 10.1007/s11465-006-0046-7

摘要： The rhythmic locomotion of a creature is a self-excitation behavior of the CPG (central pattern generator), which makes it supremely adapted for environment. Based on this fact, firstly, a snake-ike robot controller with cyclic inhibitory CPG model was designed, and then the stability of a single neuron, CPG model and the NON ( neuron oscillator network) was analyzed. By implementing this control architecture to a simulator based on the mechanical dynamics of a real snake-like robot named Perambulator-I, we presented preliminary rules for parameter setting of the CPG controller to modulate the number of S shapes, the curve of the body shape, locomotion velocity, and the curve of the locomotion trajectory for serpentine locomotion. Moreover, we demonstrated that Perambulator-I can successfully exhibit serpentine locomotion by using the output of the proposed CPG controller. The results of this paper provide a realistic approach for designing an artificial CPG controller.
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Solvates and polymorphs of clindamycin phosphate: Structural, thermal stability and moisture stability

Junbo Gong, Dejiang Zhang, Yuanyuan Ran, Keke Zhang, Shichao Du

《化学科学与工程前沿（英文）》 2017年 第11卷 第2期   页码 220-230 doi: 10.1007/s11705-017-1624-4

摘要： Clindamycin phosphate (CP), an antibacterial agent, has been reported to form several solid-state forms. The crystal structures of two CP solvates, a dimethyl sulfoxide (DMSO) solvate and a methanol/water solvate (solvate V), have been determined by single crystal X-ray diffraction. The properties and transformations of these forms were characterized by powder X-ray diffraction, Single-crystal X-ray diffraction, differential scanning calorimetry, thermo gravimetric analysis, hot-stage microscopy, and dynamic vapor sorption. Very different hydrogen bonding networks exist among the host-host and host-solvent molecules in the two crystal structures, resulting in different moisture stabilities. The thermal stabilities of the two solvates upon heating and desolvation were also studied. When the temperature was above the boiling point of methanol, solvate V converted to a polymorphic phase after a one step desolvation process, whereas the desolvation temperature of the DMSO solvate was below the boiling point of DMSO. At the relative humidity above 43%, the DMSO solvate transformed to a hydrate at 25 °C. In contrast, solvate V did not transform at any of the humidities studied.

关键词： clindamycin phosphate     solvate     crystal structure     thermal stability     moisture stability    

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Space-time evolution rules study on acoustic emission location in rock under cyclic loading

Jiang XU, Shuchun LI, Yunqi TAO, Yongdong JIANG, Xiaojun TANG,

《结构与土木工程前沿（英文）》 2009年 第3卷 第4期   页码 422-427 doi: 10.1007/s11709-009-0056-8

摘要： An acoustic emission (AE) location experiment was performed on sandstone using an advanced AE test system. The space-time evolution rule regarding damage was analyzed under cyclic loading as well as AE. The results show that AE on static loading process is consistent with the damage evolution rule of compression and the elastic-plastic deformation phase; at the beginning of cyclic loading with low duration time and energy, AE events came from a small crack. The location result showed that most events occurred in the core zone forming at the static loading process, and the location points changed slowly. AE energy changed little during the metaphase of cyclic process. There was a modest increase of location points in every cycle. The tendency of steady development could be predicted from the AE location events. At the end of each cyclic loading, the quantity of AE events and energy increased quite rapidly, reaching a maximum at the last cycle. AE events had high energy and duration time. Location events changed quite rapidly and assembled and linked continuously in the core zone. At the same time, they expanded to the top of specimen. A macroscopic crack finally formed. In the postfailure process, some AE events still existed due to fracturing of gliding friction. Owing to the inner stress balance of rock even after loading stopped, minor AE events still occurred.

关键词： location result     AE location     consistent     friction     elastic-plastic deformation    

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标题 作者 时间 类型 操作

Construction of nitrogen-doped carbon cladding LiMnO film electrode with enhanced stability for electrochemically

期刊论文

An enhanced damage plasticity model for predicting the cyclic behavior of plain concrete under multiaxial

Mohammad Reza AZADI KAKAVAND, Ertugrul TACIROGLU

期刊论文

Isogeometric analysis of coupled thermo-elastodynamic problems under cyclic thermal shock

Asghar AMANI DASHLEJEH

期刊论文

Prediction of cyclic large plasticity for prestrained structural steel using only tensile coupon tests

Liang-Jiu JIA, Tsuyoshi KOYAMA, Hitoshi KUWAMURA

期刊论文

循环双谱及在周期平稳类故障中的应用

苏中元,贾民平,许飞云,胡建中

期刊论文

Experimental research on seismic behavior of recycled concrete frame under varying cyclic loading

SUN Yuedong, XIAO Jianzhuang, ZHOU Deyuan

期刊论文

Cyclic behavior of prefabricated reinforced concrete frame with infill slit shear walls

Kui XIAO,Qilin ZHANG,Bin JIA

期刊论文

特高含水期分层段周期注采技术研究与实践认识

姜振海

期刊论文

Experimental investigation of the influence on static and cyclic deformation of structural soft clay

CHEN Yunmin, CHEN Yingping, HUANG Bo

期刊论文

Numerical evaluation of group-pile foundation subjected to cyclic horizontal load

Youngji JIN, Xiaohua BAO, Yoshimitsu KONDO, Feng ZHANG,

期刊论文

Compressive and cyclic flexural response of double-hooked-end steel fiber reinforced concrete

Demewoz W. MENNA; Aikaterini S. GENIKOMSOU; Mark F. GREEN

期刊论文

Seismic response of precast reinforced concrete wall subjected to cyclic in-plane and constant out-of-plane

期刊论文

Design of a cyclic inhibitory CPG controller for the locomotion of a snakelike robot

LU Zhen-li, MA Shu-gen, LI Bin, WANG Yue-chao

期刊论文

Solvates and polymorphs of clindamycin phosphate: Structural, thermal stability and moisture stability

Junbo Gong, Dejiang Zhang, Yuanyuan Ran, Keke Zhang, Shichao Du

期刊论文

Space-time evolution rules study on acoustic emission location in rock under cyclic loading

Jiang XU, Shuchun LI, Yunqi TAO, Yongdong JIANG, Xiaojun TANG,

期刊论文